Visual Studio has a ton of Keyboard shortcuts built in. In fact, there are HUGE PDF Prints available for VS2005 C# and Visual Basic, as well as VS2008 C# and VS2008 Visual Basic. If you want to change or add to the current keyboard shortcuts, this video shows you how.
One of the first custom keyboard shortcuts I add is [CTRL]+[ALT]+[P]. This shortcut isn’t used for anything, so I’m not overriding anything built in, but I bind it to “Debug.AttachToProcess” which is much faster than navigating to Debug | Attach to Process.